Citric Acid Passivation - Obtaining Method For
Introduction In certain applications such as the medical industry along with the semiconductor industry, utilize of of highly pure, corrosion and contaminant free stainless steel is required. Stainless steel tubing and fittings for the transportation of process gases and surgical stainless steel are examples. A key process step that will mean that components such because these remain contaminant and corrosion free could be the cleaning and 'passivation' of the metal surfaces. A process using citric acid (as opposed to mineral acids pertaining to example nitric acid) is normally considered superior. Austenitic stainless steel is a form of carbon steel in the neighborhood . often used due to applications because of its high ductility, low yield stress and relatively high ultimate tensile strength. Under most conditions that these porn files has good corrosion resistance, but capable to achieve suitable performance under all conditions it is necessary for the surface of the steel with regard to properly prepared. Citric acid passivation is a process used by WS Associates to particular the components manufactured are suitable for replacements in both the medical and semiconductor fields. Why use citric acid to clean and passivate stainless steel components? Austenite steel a good allotrope of steel formed by hearing steel to a healthy temperature and then cooling rapidly. Approach changes the crystal structure of the metal from body centered cubic to deal with centered cubic. Type 304 surgical stainless steel is austenitic steel containing 18-20% chromium and 8-10% nickel. Once it is properly cleaned and passivated austenitic stainless steel is highly resistive to corrosion and contamination. Without cleaning however even this kind of stainless steel can begin the process of corrosion and once corrosion starts just gets worse, being continuous and self-catalyzing. Cleaning and passivating is why any impurities have been removed as well as the creation associated with the outer oxide layer that protects the metal from future corrosion has been created - this will be the 'passivation' film. Stainless steel is primarily iron alloyed with small quantities of chromium, nickel and sometimes molybdenum and manganese along with other equipment. Corrosion resistance is engendered by the formation a good outer layer consisting of oxides of chromium, iron and nickel, which don't corrode. Interesting passivation layer is achieved by maximizing the oxides of chromium. There are two key elements to the development of a successful passivation shell. First all impurities, such as grease a different organics, that can prevent oxidation must be removed. Secondly, the oxidation must be permitted to complete so there are no free iron atoms on leading. In the past acids such as nitric acid have been used extensively to passivate stainless steel, however there several disadvantages to nitric acid. Nitric acid is corrosive by nature, a health hazard and this is hard to dispose regarding. In many cases free iron could be redeposited inside the surface again and nitric acid furthermore known to supply pitting corrosion. There are many issues with long term use of mineral acid applications, especially under corrosive environments. If the nitric acid is heated then these problems are increased. Despite these difficulties lots of companies continue incorporated with this nitric acid at least for a part of the passivation process. Citric acid cleaning and passivation process on the opposite hand is fairly safe and environmentally friendly since citric acid is there in many fruits and that is used by anaerobic organisms as part of the process for creating energy. Citric acid is thus non toxic, non corrosive and biodegradable, and may also often be disposed of relatively easily, usually in the sewer system without extensive pre-treatment. Citric acid has that will have numerous including: The passivated surfaces will pass all the required tests including salt spray and high humidity. The citric acid operates by creating complex molecules that bind up many metallic ions to have influence of reducing the corrosion resistance of the stainless aluminum. These complex molecules are commonly water soluble in the aqueous solution in that this citric acid is dissolved and they will not redeposit metal ions as mineral acids are acknowledged to to follow. The citric acid also works to enhance the chromium concentration at the surface of the metal. The citric acid passivation process is necessary very successfully in the pharmaceutical, medical and semiconductor industries, and produces superior leads to the utilization of nitric acid alone, offers continued available for historical reasons. Current studies for the surface chemistry of stainless steel shows that citric acid passivation eliminates the contaminants from the surface more completely and enables you to produce a totally passive surface by giving the best chromium enrichment to leading. Conclusion Citric acid cleaning and passivation your state-of-the-art technology that is extremely effective in stainless steel passivation. The use of nitric acid has several well know drawbacks and only has continued being used because of industry inertia. At WS Associates manufacturing facilities citric acid passivation processes happen to developed, producing a safe, effective and economical stainless steel passivation process for the semiconductor industry, medical field and other industries.